It is the second meeting of Liverpool and Arsenal within a week as the Reds host the Gunners at Anfield on Thursday night in the Carabao Cup.
Jurgen Klopp’s side won the Monday night match 3-1 in the Premier League as goals from Andrew Robertson, Sadio Mane and Diogo Jota cancelled out an opener from Alexandre Lacazette.
Already into the quarter-finals are Tottenham, Manchester United, Man City, Newcastle and Everton, while Brentford host Fulham and Aston Villa play Stoke in the other fourth round ties on Thursday night.
When is Liverpool vs Arsenal?
The match kicks-off at 7.45pm on Thursday 1 October.
What TV channel is Liverpool vs Arsenal on and is there a live stream?
Sky Sports Main Event and Sky Sports Football will be showing the game live with coverage starting at 7.30pm.
Subscribers can stream the action on the Sky Sports app and Sky Go.
Liverpool vs Arsenal team news
Both teams will be making multiple changes from their Premier League sides.
Youngsters such as Curtis Jones, Harvey Elliott and Neco Williams will come in for Liverpool, but Thiago Alcantara, Alex Oxlade-Chamberlain, Kostas Tsimikas and Jordan Henderson are all out.
Arsenal may welcome back Sokratis and Cedric Soares after they returned to training from calf injuries.
Liverpool vs Arsenal odds
17/20 Liverpool
16/5 Draw
3/1 Arsenal
Odds courtesy of Betfair
MORE: Liverpool ‘know what Arsenal are going to do’ in Carabao Cup clash, says Curtis Jones
MORE: Arsenal ready another bid for Houssem Aouar as Lyon star pushes for move
Follow Metro Sport across our social channels, on Facebook, Twitter and Instagram.
For more stories like this, check our sport page.