Former American Footballer OJ was cleared of the murders of his wife Nicole Brown and her friend Ron Goldman back in a trial in 1995.
On his defence team was Robert Kardashian – the late husband of Kris Jenner and father of Kourtney, Kim, Khloe and Rob.
Caitlyn was married to Kris during the trial, so it seems Myles may be hoping she has some inside gossip on the trial.
The 28-year-old said: “The first thing I’m going to ask Caitlyn is, ‘Did OJ do it Does the glove really fit?”
In the trial, OJ was asked to try on a pair of gloves which had allegedly been used during the murders.
However it seems true crime isn’t the only type of story on Myles’ mind – love is too.
Speaking of getting a link up from Caitlyn with her daughters Kendall and Kylie Jenner, Myles added to the Sun: “They’re beautiful people, but personally Kendall is naturally stunning. She’s phenomenal.”
And he’s looking forward to meeting Girls Aloud star Nadine Coyle too, who will be one of his other fellow campmates.
He said: “I know Nadine, everyone knows Nadine. She’s a beautiful lady.”
Myles, Caitlyn and Nadine will be joined by seven other celebrities in the jungle – Adele Roberts, Andrew Maxwell, Ian Wright, Jacqueline Jossa, James Haskell, Kate Garraway and Roman Kemp.
The series kicks off tomorrow night (Sunday), with the stars making their way into their temporary new home already.
There has already been a sneak glimpse of the first trial, which sees the famous faces forced to walk a plank suspended over the edge of a high rise building.
There was also a swimming challenge and helicopters involved.
I’m a Celebrity… Get Me Out of Here! kicks off tomorrow night at 9pm on ITV